3-Nitrophenylboronic acid 3-硝基苯硼酸

规格: 98%
CAS: 13331-27-6
产品编号: H62814
MDL: MFCD00007193
品牌: INFI
Chemical Name3-Nitrophenylboronic acid
CAS Number13331-27-6
Alfabeta NameNITROPHENYLBORONICACID 3-
MDL NumberMFCD00007193
Synonym 3-Nitrobenzeneboronic acid 3-硝基苯基硼酸,间硝基苯硼酸 3-硝基苯基硼酸;间硝基苯硼酸 3-硝基苯硼酸 NSC 401539 NSC 59739 m-Nitrobenzeneboronic acid m-Nitrophenylboronic acid 间硝基苯硼酸
Beilstein Registry Number2938638
PubChem Substance ID87573882
Reaxys-RN2938638
EC Number250-023-7
Chemical Name Translation3-硝基苯硼酸
InChIKeyZNRGSYUVFVNSAW-UHFFFAOYSA-N
Wiswesser Line NotationWNR CBQQ
LabNetwork Molecule IDLN00009375
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#01859

Warnings IRRITANT
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
    WGK Germany3
    Signal word Warning
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Hazard Codes Xi
      RTECSCY8980000
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S37 Wear suitable gloves 戴适当手套；
      • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition 易吸潮，密封保存。 Hygroscopic
        • 催化炔二羰基化合物的烯碳环化反应。
        • {SA} Beil. 16 ,IV,1670
        • {ALD} Beilstein:16(3)1276
        • {ALFA} Mild Lewis acid catayst, for example in the selective transesterific
        • {ALF} Mild Lewis acid catayst, for example in the selective transesterification of ß-keto esters: Synlett, 415 (2006). See also 3,4,5-Trifluorobenzeneboronic acid, L18519. For reactions of boronic acids, see Appendix 5.
        • {ALF} Oxidative conversion of arylboronic acids to phenols with potassium monopersulfate in buffered aqueous acetone (in situ dimethyldioxirane) is exemplified for this compound: Tetrahedron Lett., 36, 5117 (1995).
        • {ALF} Reagent for derivatization of diols and diamines for GC: Chromatographia, 11, 347 (1978).
        • {} {A
          • 13331-27-6 H62814 3-Nitrophenylboronic acid 3-硝基苯硼酸

          化学属性

          Mol. FormulaC6H6BNO4
          Mol. Weight167
          Melting Point284-285
          TSCAT
          Density1.4
          Solubility溶于热水
          Stability易吸潮

          *以上化合物性质及应用等信息仅供参考