Chemical Name | Copper(I) Iodide |
Synonym |
Cuprous iodide
{LY} Cuprous iodide
{} {LY} Cuprous iodide
{} {} {LY} Cuprous iodide
{} {} {} {LY} Cuprous iodide
{} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {} {} {} {
{} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {} {} {} {}
{} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
{} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cuprous iodide |
CAS Number | 7681-65-4 |
PubChem Substance ID | 6432705 |
EC Number | 231-674-6 |
MDL Number | MFCD00010978 |
Beilstein Registry Number | 2384789 |
Merck Number | 14,2662 |
Chemical Name Translation | 碘化亚铜(I) |
LabNetwork Molecule ID | LN00192893 |
InChI | InChI=1S/Cu.HI/h;1H/q+1;/p-1 |
Canonical SMILES | [Cu]I |
GHS Symbol
WGK Germany | 3 |
Hazard Codes |
|
Hazard statements | |
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H302 Harmful if swallowed 吞食有害
- H319 Causes serious eye irritation 严重刺激眼睛
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H318 Causes serious eye damage 严重伤害眼睛
|
Personal Protective Equipment |
dust mask type N95 (US), Eyeshields, Gloves |
Precautionary statements | |
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
Signal word |
Danger |
Safety Statements | |
|
Risk Statements | |
|
Storage condition |
RT, stored under nitrogen, away from moisture
{LY} RT, stored under nitrogen, away from moisture
{} {LY} RT, stored under nitrogen, away from moisture
{} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture
{} {} {} {} {} {} {} {} {} {} {} {} |
UN Number |
UN3077 |
Packing Group | III |
有机反应催化剂,与碘化汞同用,作为测定机械轴承温度升高的指示剂。
{uni_hamburg} Short: II/24A
{ALFA} Has been used in an improved Ullmann synthesis of diaryl ethers with ultrasound activation: J. Chem. Soc., Perkin 1, 407 (1992), and also as a catalyst for the arylation of active methylene compounds: Synthesis, 67 (1983); J. Org. Chem., 58, 7606 (1993).
{ALFA} The formation of Cu(I) acetylides from terminal acetylenes, and their coupling with aryl or vinyl iodides, known as the Castro-Stephens reaction: J. Org. Chem., 28, 3313 (1963), is more often now carried out in situ with a Pd catalyst (the Sonogashira coupling), e.g. with trans-Dichlorobis(triphenyl­phosphine)­palladium(II)­, 10491: Tetrahedron Lett., 4467 (1975); J. Org. Chem., 63, 8551 (1998), or Tetrakis(triphenyl­phosphine)­palladium(0)­, 10548: Tetrahedron Lett., 30, 6997 (1989); Org. Synth. Coll., 9, 117 (1998); Synlett, 1387 (1998).
{ALFA} Precursor of organocopper reagents. Forms a 1:1-complex with triethyl phosphite, useful in the preparation of unsymmetrical biaryls by a room-temperature Ullmann-type coupling reaction: J. Am. Chem. Soc., 98, 8282 (1976); Tetrahedron Lett., 2767 (1978). For list of examples, see: Org. Synth. Coll., 8, 586 (1993).
{ALD} Merck: 14,2662