Bis(cyclopentadienyl)zirconium dichloride 二氯二茂锆

规格: 98%
CAS: 1291-32-3
产品编号: H76122
MDL: MFCD00003726
品牌: INFI
Chemical NameBis(cyclopentadienyl)zirconium dichloride
Synonym Bis(cyclopentadienyl)zirconium(IV) dichloride
CAS Number1291-32-3
EC Number215-066-8
Beilstein Registry Number2384789
MDL NumberMFCD00003726
PubChem Substance ID87577925
Chemical Name Translation二氯二茂锆
Wiswesser Line NotationL50J 0-ZR-GG- 0L50J
LabNetwork Molecule IDLN01746727
Canonical SMILES[][Zr](Cl)(Cl)[].c1cccc1.c2cccc2
  • 用于合成许多早期过渡金属络合物和有机金属化合物
  • {uni_hamburg} Short: III/35D5
  • {ALF}
  • {uni_hamburg} Short: III/20b
  • {ALF} For reaction of alkene-zirconocene complexes with cyclic enol ethers, see: Angew. Chem. Int. Ed., 43, 3932 (2004).
  • {ALF} Versatile organometallic reagent and catalyst. For a brief review, see: Synlett, 375 (1999). Other reviews: Organozirconium compounds in organic synthesis: Synthesis, 1 (1988); Recent advances in the chemistry of zirconocene and related compounds: Tetrahedron, 51, 4255 (1995); Synthetic applications of zirconocene complexes: Tetrahedron, 52, 12853 (1996). Formation of carbon-carbon bonds via 'zirconocene' (obtained by reaction of the dichloride with Grignard or lithium reagents): Synlett, 299 (1995). Reduction with n-BuLi in the presence of 2-butyne leads to a zirconium metallocycle: Tetrahedron Lett., 27, 2829 (1986), which is a useful intermediate for the synthesis of phospholes and analogous heterocycles in which the Zr atom is replaced by As, Sb, Bi, Si, Ge, Sn, Ga, S, Se or B: Org. Synth. Coll., 9, 653 (1998), and references therein:
    • 1291-32-3 H76122 Bis(cyclopentadienyl)zirconium dichloride 二氯二茂锆

    化学属性

    Mol. FormulaC10H10Cl2Zr
    Mol. Weight292.32
    Density1.422
    Melting Point242-245°C
    TSCAYes
    Boiling Point124-125 °C at 15 mmHg
    Solubility水解
    Stability对湿度敏感
    Flash Point124-125°C/15mm
    Appearance white to off-white pwdr.
    RedoxReduction

    *以上化合物性质及应用等信息仅供参考