| Chemical Name | Ammonium persulfate |
| Synonym |
AMMONIUM PEROXODISULFATE
AMMONIUM PEROXYDISULFATE
AMMONIUM PEROXYDISULPHATE
AMMONIUM PERSULFATE
AMMONIUM PERSULPHATE
AP
AP APS PER 过二硫酸铵 过氧二硫酸铵
APS
Ammonium Persulfate
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| CAS Number | 7727-54-0 |
| PubChem Substance ID | 62648 |
| EC Number | 231-786-5 |
| MDL Number | MFCD00003390 |
| Reaxys-RN | 11343687 |
| Merck Number | 541 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 过硫酸铵 |
| Wiswesser Line Notation | H2 S2-O8 &QH 2 |
| LabNetwork Molecule ID | LN00196313 |
| InChI | InChI=1S/2H3N.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h2*1H3;(H,1,2,3)(H,4,5,6) |
| Canonical SMILES | [NH4+].[NH4+].[O-]S(=O)(=O)OOS(=O)(=O)[O-] |
GHS Symbol
| WGK Germany | 1 |
| Hazard Codes |
5.1
O;Xn |
| Hazard statements | |
- H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
- H302 Harmful if swallowed 吞食有害
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H319 Causes serious eye irritation 严重刺激眼睛
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H335 May cause respiratory irritation 可能导致呼吸道刺激
|
| Personal Protective Equipment |
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
| RTECS | SE0350000 |
| Precautionary statements | |
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施,避免与可燃物混合/...
- P233 Keep container tightly closed. ?保持容器密闭。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P264+P265
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下,戴呼吸防护。
- P301+P312
- P301+P312+P330
- P301+P317
- P302+P350
- P302+P352
- P302+P352+P333+P313+P362+P364
- P304+P340
- P304+P341
- P305+P351+P338
- P308+P316
- P309+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
- P319
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P330 Rinse mouth. 漱口
- P332+P313
- P332+P317
- P333+P313
- P333+P317
- P337+P313
- P337+P317
- P342+P311
- P342+P316
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P362+P364
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403 Store in a well-ventilated place. 储存在通风良好的地方。
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
|
| Signal word |
Danger |
| UN Number |
1444
UN 1444 5.1/PG 3
UN1444 |
| Risk Statements | |
- R22 Harmful if swallowed 吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R42/43
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
|
| Safety Statements | |
- S22 Do not breathe dust 不要吸入粉尘;
- S24 Avoid contact with skin 避免皮肤接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S37 Wear suitable gloves 戴适当手套;
|
| Storage condition |
+20°C
+20℃
20
20℃
Moisture Sensitive
Store at RT.
密封避光阴凉处保存。防止有机物接触 |
| Packing Group | III |
| Hazard Class | 5.1 |
| Warnings |
危化品目录(2015) |
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 689 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
Industrial Hygienists, Inc., 1986 Volume(issue)/page/year: 5,468,1986
| Restrict |
危险品 |
检定及测定锰,钢铁分析,氧化剂。
{ALF} In combination with AgNO3 and Cu(OAc)2, promotes a carbamoyl radical process for the conversion of oxalic acid monoamides to isocyanates: J. Org. Chem., 60, 5430 (1995).
{ALD} Merck: 14,541