Chemical Name | Lead tetraacetate |
Synonym |
acetic acid; lead(IV) salt
leadtetracetate
铅糖、乙酸铅
四醋酸铅,乙酸高铅
lead tetracetate
LEAD TETRAACETATE
Plumbic acetate
乙酸铅(IV);乙酸高铅;四醋酸铅;醋酸高铅;乙酸高铅盐
lead (IV) acetate
lead tetra-acetate
Lead(IV) tetraacetate
乙酸高铅盐
PB(ACAC)4
lead tetra acetate
四乙酸鉛
Aceticacid,lead(4+)salt
Leadacetateaceticacidwhitetolightbrownxtl
Lead acetate [Pb(OAc)4]
乙酸铅(IV), 96%(DRY WT.), STAB. WITH 5-10% GLACIAL ACETIC
四乙酸铅
乙酸高铅盐,醋酸高铅
Blei(IV)acetat
Lead tetraacetate
4
乙酸鉛(IV)
Bleitetraacetat
Pb(acac)4 四乙酸铅
乙酸铅(Ⅳ)
LTA
四醋酸铅
四醋酸鉛
乙酸高铅
Tetrakis(acetyloxy)plumbane
LEAD(+4)ACETATE
乙酸铅(IV)
tetra-leadacetat
Lead(IV) acetate
LEAD(IV) TETRAACETATE
Blei(IV)-acetat (angefeuchtet mit Essigsäure)
Pb(acac)
LEAD(IV) ACETATE GM
LEAD(IV) ACETATE
aceticacid,lead(4++)salt
Leadtetraacetate
Blei(IV)-acetat
LEAD ACETATE
leadacetate(pb(oac)4)
leadacetate(pb(o2c2h3)4)
plumbicacetate
Lead(IV) acetate (5-10% acetic acid)
Lead acetate (Pb(O2C2H3)4)
醋酸高铅
醋酸铅
Acetic acid, lead(4+) salt |
Beilstein Registry Number | 3595640 |
PubChem Substance ID | 9846230 |
CAS Number | 546-67-8 |
MDL Number | MFCD00008693 |
EC Number | 208-908-0 |
Merck Number | 5423 |
Chemical Name Translation | 四乙酸铅 |
Reaxys-RN | 3595640 |
LabNetwork Molecule ID | LN00841725 |
InChI | InChI=1S/4C2H4O2.Pb/c4*1-2(3)4;/h4*1H3,(H,3,4);/p-4 |
Precautionary statements | |
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P332+P313
- P301+P312+P330
- P302+P350
- P308+P313
- P302+P352+P332+P313+P362+P364
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施,避免与可燃物混合/...
- P304+P340+P312
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P273 Avoid release to the environment. 避免释放到环境中。
|
Personal Protective Equipment |
Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
GHS Symbol
Signal word |
Danger |
Hazard statements | |
- H332 Harmful if inhaled 吸入有害
- H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H302 Harmful if swallowed 吞食有害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
|
Hazard Codes |
T,N
T,N,O
O,T,N
T;N |
WGK Germany | 3 |
RTECS | AI5300000 |
Safety Statements | |
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S17 Keep away from combustible material 远离可燃物料;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
|
Packing Group | III |
UN Number |
UN1616
UN 2923 8/PG 2
2923
3087 |
Risk Statements | |
- R33 Danger of cumulative effects 有累积作用的危险
- R61 May cause harm to the unborn child 可能对未出生的婴儿导致伤害
- R62 Possible risk of impaired fertility 有削弱生殖能力的危险
- R48/22
- R50/53
- R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
- R35 Causes severe burns 会导致严重灼伤
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
|
Storage condition |
Moisture Sensitive
0-10°C
0-6°C
易吸潮,密封保存。
储存温度2-8℃
密封保存,储存温度2-8℃
储存温度2-8℃,充氩储存 |
Hazard Class | 5.1/6.1 |
有机合成中的选择性氧化剂。
{ALF} N-Formylanilines are oxidized to isocyanates. In the presence of methanol, the reaction affords the methyl urethanes directly: Synthesis, 225 (1982).
{ALF} Carboxylic acids undergo oxidative decarboxylation; review: Org. React., 19, 279 (1972). In the presence of LiCl, the alkyl chloride is obtained (Kochi reaction): J. Am. Chem. Soc., 87, 2500 (1965); Synth. Commun., 20, 1011 (1990). Yields are lower for the bromide and iodide, cf Hunsdiecker reaction (see Mercury(II)­ oxide, A16157). Use of NCS allows successful scale-up: Synthesis, 493 (1973).
{ALD} Merck:14,5423
Beilstein: 2,IV,118
{ALF} Intramo
{uni_hamburg} Short: EINECS
{uni_hamburg} Short: III/10a
{ALF} Versatile oxidizing agent and source of acetoxy radicals. For a review of one-step acetoxylation at carbon, see: Synthesis, 567 (1973). See also: M. Hudlicky, Oxidations in Organic Chemistry, ACS Monograph 186, Washington DC (1990). Oxidizes silyl enol ethers to ɑ-acetoxycarbonyl compounds in high yields: Tetrahedron, 39, 861 (1983). In combination with a metal halide, enol ethers are similarly converted to ɑ-halocarbonyl compounds: Synthesis, 1021 (1982).
{ALD} Merck:14,5423
{ALF} Cleaves vic-glycols to carbonyl compounds; see, e.g.: Org. Synth. Coll., 4, 124 (1963).