Diphenylsilane 二苯基硅烷

规格: 98%
CAS: 775-12-2
产品编号: H83645
MDL: MFCD00003002
品牌: INFI
Chemical NameDiphenylsilane
Synonym Diphenylsilane {LY} Diphenylsilane {} {LY} Diphenylsilane {} {} {LY} Diphenylsilane {} {} {} {LY} Diphenylsilane {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diphenylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {
CAS Number775-12-2
EC Number212-271-4
Beilstein Registry Number2935887
MDL NumberMFCD00003002
PubChem Substance ID24848906
Reaxys-RN2935887
Chemical Name Translation二苯基硅烷
InChIKeyVDCSGNNYCFPWFK-UHFFFAOYSA-N
LabNetwork Molecule IDLN00202555
Canonical SMILESC1([SiH2]C2=CC=CC=C2)=CC=CC=C1
GHS Symbol
Signal word Warning
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
    Risk Statements
    • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
      Precautionary statements
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P302+P352
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P332+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
        Hazard statements
        • H315 Causes skin irritation 会刺激皮肤
          Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes Xi
          Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro
        • {ALF} CsF promotes the reduction of aldehydes and ketones to alcohols: J. Organomet. Chem., 148, C1 (1978); 172, 143 (1979). Esters can be reduced at elevated temperatures: Synthesis, 558 (1981). Aldehydes and ketones are also reduced in the presence of TBAF: J. Org. Chem., 53, 5415 (1988).
        • {ALF} In combination with an equivalent of Titanium(IV)­ isopropoxide, A13703, a mild, one-pot reduction of tertiary amides to aldehydes can be accomplished in high yield. The initial product is the enamine which can be readily hydrolyzed in situ to the aldehyde: Angew. Chem. Int. Ed., 35, 1515 (1996):
        • {ALF} In the presence of Tetrakis(triphenyl­phosphine)­palladium(0)­, 10548, effects the reductive cleavage of allylic acetates: J. Org. Chem., 48, 3545 (1983). With the same catalyst and a Lewis acid such as zinc chloride, ɑß-unsaturated aldehydes, ketones and esters are reduced to their saturated counterparts: J. Am. Chem. Soc., 108, 7314 (1986).
        • {ALF} Protection of diols as diphenylsilylenes can be effected in the presence of CsF: J. Organomet. Chem., 282, 155 (1985). See Diphenyl­dichlorosilane, A12051, and Appendix 4.
        • {ALF} Reducing agent used in combination with F- or other catalyst.
        • {uni_hamburg} Short: III/35C4
        • {uni_hamburg} Short: III/35D2
          • 775-12-2 H83645 Diphenylsilane 二苯基硅烷

          化学属性

          Mol. FormulaC12H12Si
          Mol. Weight184.31
          Density0.993
          Refractive indexn20/D 1.579(lit.)
          Boiling Point95-97 °C at 13 mmHg
          Flash Point98°C
          TSCAYes
          Melting Point79 ºC (SOLV: PENTANE)

          *以上化合物性质及应用等信息仅供参考