Benzyl mercaptan 苄硫醇

规格: 98%
CAS: 100-53-8
产品编号: H83908
MDL: MFCD00004867
品牌: INFI
Chemical NameBenzyl Mercaptan
CAS Number100-53-8
EC Number202-862-5
Beilstein Registry Number605864
MDL NumberMFCD00004867
Synonym -Toluenethiol A-TOLUENETHIOL ALPHA-TOLUENETHIOL BENZYL MERCAPTAN Benzenemethanethiol Methanethiol, phenyl- Phenylmethanthiol TOLUENETHIOL Toluene-a-thiol a-Toluenethiol alpha-Mercaptotoluene alpha-Toluolthiol alpha-mercapto-toluen b benzenemethanethiol benzyl mercaptane benzylthiol phenyl-methanethio thiobenzyl alcohol toluene a-thiol toluene α-thiol toluene-a-thiol {} {} {} {} {} {} {uni α-Toluenethiol α-Toluolthiol α-mercaptotoluene α-甲苯硫醇 Benzenemethanethiol 甲苯硫醇 α-甲苯硫醇 甲苯硫醇 卞基硫醇 苄硫醇
PubChem Substance ID87576262
Merck Number9322
Reaxys-RN605864
Chemical Name Translation苄硫醇
Wiswesser Line NotationSH1R
LabNetwork Molecule IDLN00164270
InChIInChI=1S/C7H8S/c8-6-7-4-2-1-3-5-7/h1-5,8H,6H2
GHS Symbol
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 16 gm/kg/26W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Tumorigenic - tumors at site of application
REFERENCE :
   AJCAA7 American Journal of Cancer.  (New York, NY)  V.15-40, 1931-40.  For
   publisher information, see CNREA8.  Volume(issue)/page/year: 15,2149,1931

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 373 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
   Behavioral - coma
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 493 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
   Behavioral - coma
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 178 ppm/4H
TOXIC EFFECTS :
   Behavioral - muscle weakness
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   19,171,1958

Signal word Danger
WGK Germany3
Safety Statements
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
    Risk Statements
    • R22 Harmful if swallowed 吞咽有害
    • R23 Toxic by inhalation 吸入有毒
    • R50/53
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
      • P273 Avoid release to the environment. 避免释放到环境中。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
      • P301+P312+P330
      • P302+P350
      • P302+P352+P332+P313+P362+P364
      • P304+P340+P310
      • P305+P351+P338
      • P305+P351+P338+P337+P313
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P337+P313
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P370+P378
      • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
      • P403+P233
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H227 Combustible liquid 可燃液体
        • H302 Harmful if swallowed 吞食有害
        • H330 Fatal if inhaled 吸入致命
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          RTECSXT8650000
          Packing GroupIII
          UN Number 2810 3334 UN2810
          Storage condition 充氩储存 对空气敏感，密封保存 Air Sensitive
          Hazard Codes 6.1 9 T
          Hazard Class6.1
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 有机合成中间体。
        • {uni_hamburg} Short: II/27B
        • {ALD} Merck:14,9322
        • {ALD} Merck:14,9322
        • Beilstein:6,453
        • {uni_hamburg} Short: III/38B
          • 100-53-8 H83908 Benzyl mercaptan 苄硫醇

          化学属性

          Mol. FormulaC6H5CH2SH
          Mol. Weight124.0
          Density1.048
          Refractive index1.5750 to 1.5770
          Vapor Density>;4 (vs air)
          Boiling Point194 - 195℃
          Flash Point70 ℃
          TSCAYes
          Melting Point-29ºC
          Solubility不溶于水，溶于乙醇、二硫化碳。
          Stability对空气敏感

          *以上化合物性质及应用等信息仅供参考