Diethylamine 二乙胺

规格: 99%
CAS: 109-89-7
产品编号: H89202
MDL: MFCD00009032
品牌: INFI
Chemical NameDiethylamine
MDL NumberMFCD00009032
CAS Number109-89-7
Synonym 氨基二乙胺 N-Ethylethanamine; N,N-Diethylamine; DEA N,N-Diethylamine Dwuetyloamina ethanamine,n-ethyl diethylamine C4H11N (diethylamine) DEA N,N-Diethylamin n-ethyl-ethanamin Diaethylamin (C2H5)2NH 二乙胺 N-Ethylethanamine Ethanamine, N-ethyl- Dietilamina N-乙基乙胺 Diethyl-amine 氨基二乙烷,N-乙基乙胺 二乙基胺 Diethamine DIISOPROPYLAMINE, >=99.5% Diäthylamin ai3-24215 Diethyl amine N-ETHYLETHANAMINE DIETHYLAMINE N-Ethylethanemine DEN N-Ethylethylamin Diethylamine N,N'-
Beilstein Registry Number605268
EC Number203-716-3
PubChem Substance ID8021
Merck Number3111
Reaxys-RN605268
Chemical Name Translation二乙胺
Wiswesser Line Notation2M2
LabNetwork Molecule IDLN00194205
InChIInChI=1S/C4H11N/c1-3-5-4-2/h5H,3-4H2,1-2H3
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 820 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 4,119,1951

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 5000 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-    1961-
   Volume(issue)/page/year: 14,80,1975

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 20 gm/m3
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Lungs, Thorax, or Respiration - emphysema
   Liver - fatty liver degeneration
REFERENCE :
   12OVAW "Voprosy Promyshlennoi Toksikologii," Pravdin, N.S., ed., Akademiya
   Meditsinskikh Nauk-SSSR, Moscos, Russia, 1960  Volume(issue)/page/year:
   -,176,1960

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AEHLAU Archives of Environmental Health

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 400 uL/plate
REFERENCE :
   EJMBA2 Egyptian Journal of Microbiology.  (National Information and
   Documentation Centre, A1-Tahrir St., Awqaf P.O. Dokki, Cairo, Egypt)  V.7-
   1972-  Volume(issue)/page/year: 15,113,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 200 uL/plate
REFERENCE :
   EJMBA2 Egyptian Journal of Microbiology.  (National Information and
   Documentation Centre, A1-Tahrir St., Awqaf P.O. Dokki, Cairo, Egypt)  V.7-
   1972-  Volume(issue)/page/year: 15,113,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 50 uL/plate
REFERENCE :
   EJMBA2 Egyptian Journal of Microbiology.  (National Information and
   Documentation Centre, A1-Tahrir St., Awqaf P.O. Dokki, Cairo, Egypt)  V.7-
   1972-  Volume(issue)/page/year: 16,133,1981

WGK Germany1
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302+H332
  • H332 Harmful if inhaled 吸入有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302 Harmful if swallowed 吞食有害
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
    RTECSHZ8750000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P303+P361+P353
    • P303+P361+P353+P310+P363
    • P305+P351
    • P305+P351+P338
    • P308+P311
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Packing GroupII
      UN Number 1154
      Risk Statements
      • R11 Highly flammable 非常易燃
      • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
      • R35 Causes severe burns 会导致严重灼伤
      • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
        Safety Statements
        • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
        • S29 Do not empty into drains 不要排入下水道；
        • S3 Keep in a cool place 保存在阴凉处；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
          Storage condition 密封阴凉保存。 Store at RT Air Sensitive
          Hazard Codes 3 F,C
          Hazard Class3/8
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 检定锑、铂和锡，测定二硫化碳和镁，有机合成。
        • 二乙胺为溶剂和化工原料中间体，可制取药物普鲁卡因、氯喹、尼可刹米、可拉明及磺胺等类药，也可用于生产农药、染料、橡胶硫化促进剂、选矿药剂（硫氮9号）；纺织助剂、杀菌剂、缓蚀剂、阻聚剂和抗冻剂等。
        • {ALF} In combination with Lithium aluminum hydride, A18116, generates lithium tris(diethylamino)aluminum hydride, which is a useful selective reducing agent, for example: esters to aldehydes: J. Org. Chem., 52, 5486 (1987); amides to aldehydes: Tetrahedron Lett., 32, 6903 (1991).
        • {ALD} Merck:14,3111
        • {uni_hamburg} Short: II/27B
        • {ALD} Merck:14,3111
        • Beilstein:4,95
        • {uni_hamburg} Short: II/25C
        • {ALF} Alkali metal diethylamides, generated with n-BuLi or NaH, have been used for the cleavage of ethers: J. Organomet. Chem., 55, 41 (1973); Synthesis, 638 (1980), and of alkyl aryl sulfides, for which HBr and HI are usually poor: Synthesis, 583 (1982).
          • 109-89-7 H89202 Diethylamine 二乙胺

          化学属性

          Mol. FormulaC4H11N
          Mol. Weight73
          Refractive indexn20/D 1.385(lit.)
          Density0.687
          Autoignition Point594 °F
          Vapor Density2.5 (vs air)
          Boiling Point55 °C(lit.)
          Vapor Pressure14.14 psi ( 55 °C)
          Melting Point-50
          Flash Point−20 °F
          TSCAYes
          Solubility溶于水、醇、醚。
          Stability对空气敏感
          Danger-Level甲类

          *以上化合物性质及应用等信息仅供参考