Acrolein Diethyl Acetal 丙烯醛缩二乙醇

规格: 95%
CAS: 3054-95-3
产品编号: H95028
MDL: MFCD00009239
品牌: INFI
Chemical NameAcrolein Diethyl Acetal
Synonym 1,1-DIETHOXY-2-PROPENE 1,1-Diethoxy-2-propene 2-Propenaldiethylacetal 2-propenal diethyl acetal 3 3-DIETHOXYPROPENE 3 3-DIETHOXYPROPENE 99% 3,3-diethoxy-1-propen 3,3-diethoxy-propene 3,3-diethoxyprop-1-ene 3,3-diethoxypropene 3,3-二乙氧基丙烯 3，3-二乙氧基丙烯 ACROLEIN ACETAL ACROLEIN DIETHYL ACETAL Acrolein Diethyl Acetal {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00009239
CAS Number3054-95-3
EC Number221-276-0
Beilstein Registry Number1,727
PubChem Substance ID87562208
Chemical Name Translation丙烯醛缩二乙醇
Reaxys-RN1701567
Wiswesser Line Notation2OYO2&1U1
LabNetwork Molecule IDLN00196392
InChIInChI=1S/C7H14O2/c1-4-7(8-5-2)9-6-3/h4,7H,1,5-6H2,2-3H3
GHS Symbol
TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 5 ug/plate
REFERENCE :
   TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis.  (Alan R. Liss, Inc.,
   41 E. 11th St., New York, NY 10003)  V.1-    1980- Volume(issue)/page/year:
   1,259,1980

Signal word
WGK Germany3
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
    Risk Statements
    • R36 Irritating to eyes 刺激眼睛
    • R11 Highly flammable 非常易燃
      Precautionary statements
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
      • P305+P351+P338
      • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
      • P302+P352+P332+P313+P362+P364
      • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
      • P370+P378
      • P305+P351+P338+P337+P313
      • P233 Keep container tightly closed. ?保持容器密闭。
      • P241+P242+P243
      • P403+P235
        RTECSAS1370000
        Packing GroupII
        UN Number 2374
        Hazard statements
        • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
        • H319 Causes serious eye irritation 严重刺激眼睛
          Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Hazard Codes F;Xi
          Hazard Class3
          Storage condition 2-8°C 4
          Warnings 危化品目录(2015)
          Restrict 危险品
        • {ALD} Beilstein:1,727
        • {uni_hamburg} Short: III/38B
        • {uni_hamburg} Short: EINECS
        • {ALF} Heck coupling (see Palladium(II)­ acetate, 10516) occurs with aryl or vinyl bromides in the presence of morpholine or piperidine: J. Org. Chem., 46, 1061 (1981); J. Chem. Soc., Perkin 1, 2597 (1987):
        • {ALF} In the presence of acid, generates the ethoxyallyl cation which is a powerful dienophile, undergoing Diels-Alder reactions at low temperatures: J. Am. Chem. Soc., 109, 2182 (1987).
        • {ALF} Protected acrolein equivalent. Reacts with Grignard reagents (CuBr catalysis) to give predominantly (Z)-enol ethers which can be hydrolyzed to 3-substituted propionaldehydes: Tetrahedron Lett., 3833 (1975). The (E)-enol ether is formed selectively with a Ni(II)-phosphine catalyst: Chem. Lett., 351 (1985).
          • 3054-95-3 H95028 Acrolein Diethyl Acetal 丙烯醛缩二乙醇

          化学属性

          Mol. FormulaC₇H₁₄O₂
          Mol. Weight130.18
          Density0.854
          Refractive index1.4000 to 1.4030
          Flash Point15°C(lit.)
          TSCANo
          Boiling Point124°C
          Solubility不溶于水。

          *以上化合物性质及应用等信息仅供参考