Chlorotriphenylsilane 三苯基氯硅烷

规格: 98%
CAS: 76-86-8
产品编号: H98433
MDL: MFCD00000496
品牌: INFI
Chemical NameTriphenylsilyl chloride
Synonym triphenyl-chloro-silane TRIPHENLCHLOROSILANE Chlortriphenylsilan 一氯三苯基硅烷 三苯氯矽烷 triphenylchlorosilane chlorotriphenylsilane TRIPHENYLCHLOROSILANE 三苯基氯硅烷 氯三苯基硅烷 TSL 8061 silane, chlorotriphenyl- Triphenylchlorosilane,97% 氯化三苯基硅烷 TPSCl Chlorotriphenylsilane triphenylchlorosilicane Triphenylchlorosilane Triphenylsilicon chloride Triphenylchlorosilane,96% 三苯基烷基氯 Triphenylsilyl chloride 氯化三苯基硅烷,三苯基烷基氯 Chloro-triphenyl-silane Triphenylsilylchlorid silane,chlorotriphenyl- Triphenylchlorsoilane TriphenylchlorosilaneTPSCl TPSCl Triphenylchlorosilane TPSCl, Triphenylchlorosilane Triphenyltrichlorosilane Chlorotriphenylsilane; Triphenylchlorosilane TPSCL TRIPHENYLSILICON CHLORIDE Triphenylchlorosilane(Chlorotriphenylsilane) chlorotriphenyl-silan TRIPHENYLSILYL CHLORIDE Triphenylchlorsilan Silane, chlorotriphenyl- 三苯基氯硅烷, 97% Triphenylchlorosilane (TPSCl) 2,4,6-三异丙基苯磺酰氯
MDL NumberMFCD00000496
CAS Number76-86-8
PubChem Substance ID6458
Beilstein Registry Number1820487
EC Number200-989-0
Reaxys-RN1820487
Chemical Name Translation三苯基氯硅烷
InChIKeyMNKYQPOFRKPUAE-UHFFFAOYSA-N
Wiswesser Line NotationG-SI-R&R&R
LabNetwork Molecule IDLN00222616
InChIInChI=1S/C18H15ClSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#04717

WGK Germany1
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Hazard statements
    • H290 May be corrosive to metals 可能腐蚀金属。
    • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      RTECSVV2720000
      Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
      Signal word Danger
      Safety Statements
      • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
        Packing GroupII
        UN Number 1759 3261 UN 3261 8/PG 2 UN3261
        Risk Statements
        • R34 Causes burns 会导致灼伤
        • R37 Irritating to respiratory system 刺激呼吸道
          Storage condition Moisture Sensitive 0-10 充氩密封干燥保存。 0-10°C Refrigerator
          Hazard Codes 8 C
          Hazard Class8
          Warnings 危化品目录(2015)
          Restrict 危险品
        • 硅烷化试剂。制药和有机合成中间体。
        • {uni_hamburg} Short: III/35C4
        • {uni_hamburg} Short: III/35F
        • {ALF} Silylating agent: J. Chem. Soc., 3403 (1963); see Appendix 4. The stability of the bulky triphenylsilyl (TPS) ethers to basic hydrolysis is similar to TMS, but they are about 400x more stable to acid hydrolysis. Suitable conditions for their cleavage include: ethanolic NaOH; AcOH - water - THF at 70o: Chem. Lett., 1499 (1979); and TBAF: J. Am .Chem. Soc., 108, 3827 (1986).
        • {ALD} Beilstein:16(3)1208
          • 76-86-8 H98433 Chlorotriphenylsilane 三苯基氯硅烷

          化学属性

          Mol. Formula(C6H5)3SiCl
          Mol. Weight295
          Melting Point91-96
          Flash Point>200°(392°F)
          TSCAYes
          Boiling Point378
          Stability对湿度敏感
          Solubilityacetone: 0.1 g/mL, clear
          Density1.14
          pH:A

          *以上化合物性质及应用等信息仅供参考