Tetrabutylammonium hydroxide 四丁基氢氧化铵

规格: 1.0 M solution in Water, SpcSeal
CAS: 2052-49-5
产品编号: H99378
MDL: MFCD00009425
品牌: INFI
Chemical NameTetrabutylammonium hydroxide
CAS Number2052-49-5
Alfabeta NameTETRABUTYLAMMONIUMHYDROXIDE
MDL NumberMFCD00009425
PubChem Substance ID2723671
Beilstein Registry Number3571228
Reaxys-RN3571228
EC Number218-147-6
Synonym 1-Butanaminium, N-N-N-tributyl-, hydroxide 1-Butanaminium,N,N,N-tributyl-,hydroxide ;氢氧化四丁基铵溶液 ;氢氧化四丁基铵溶液;N,N,N-三丁基-1-丁铵氢氧化物 N,N,N-Tributyl-1-butanaminium hydroxide TBH TETRABUTYLAMMONIUM HYDROXIDE TETRABUTYLAMMONIUM HYDROXIDE IN WATER TETRABUTYLAMMONIUM HYDROXIDE TITRANT Tetra-n-butyl ammonium hydroxide Tetra-n-butylammonium hydroxide n,n,n-tributyl-1-butanaminiuhydroxide tetra-n-butylammonium dodecylsulfate tetra-n-butylammonium hexafluorophosphate tetrabutyl tetrabutylammonium tetrabutylammonium azide tetrabutylammonium bromide tetrabutylammonium chloride tetrabutylammonium cyanide tetrabutylammonium fluoride tetrabutylammonium hydrogen sulfate tetrabutylammonium hydroxide tetrabutylammonium iodide
Chemical Name Translation四丁基氢氧化铵
Wiswesser Line Notation4K4&4&4 &Q
LabNetwork Molecule IDLN00163724
InChIInChI=1S/C16H36N.H2O/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H2/q+1;/p-1
GHS Symbol
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 19 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 28,367,1926

Warnings 危化品目录(2015) IRRITANT
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H301+H311+H331
  • H302 Harmful if swallowed 吞食有害
  • H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H331 Toxic if inhaled 吸入中毒
  • H332 Harmful if inhaled 吸入有害
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
  • H370 Causes damage to organs 导致器官损伤
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    Hazard Codes 3 8 C F,T
    Precautionary statements
    • P201 Obtain special instructions before use. 使用前获取专门指示。
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241+P242+P243
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P264+P265
    • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P310
    • P301+P312
    • P301+P317
    • P301+P330+P331
    • P301+P330+P331+P310
    • P302+P352
    • P302+P361+P354
    • P303+P361+
    • P303+P361+P353
    • P303+P361+P353+
    • P303+P361+P353+P310+P363
    • P304+P312
    • P304+P340
    • P304+P340+P310
    • P305+P351+P338
    • P305+P351+P338+P310
    • P305+P354+P338
    • P307+P311
    • P308+P311
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P316
    • P317
    • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
    • P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
    • P330 Rinse mouth. 漱口
    • P362+P364
    • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
    • P403+P233
    • P405 Store locked up. 上锁保管。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P501a
      Signal word Danger
      RTECSBS5425000
      UN Number 2924 3267 3286
      Storage condition 充氩保存 Air Sensitive & Hygroscopic 0-10°C Air Sensitive 0-10 与酸分开存放 2-8°C
      Risk Statements
      • R11 Highly flammable 非常易燃
      • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
      • R34 Causes burns 会导致灼伤
      • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
      • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
        Safety Statements
        • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
        • S20 When using do not eat or drink 使用时，不得进食，饮水；
        • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
        • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
        • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
          Packing GroupII
          Hazard Class8
          Restrict 危险品
        • 适用于离子色谱的试剂
        • {ALF} Useful base, either as the aqueous or methanolic (see following entries) solution, compare Benzyl­trimethyl­ammonium hydroxide, A14927, for a variety of alkylation and condensation reactions; see, e.g.: Synth. Commun., 13, 927 (1983). Forms salts with many anions which may then be extracted into organic solvents: Acta Chem. Scand.: 23, 2202, 2203, 2204 (1969).
          • 2052-49-5 H99378 Tetrabutylammonium hydroxide 四丁基氢氧化铵

          化学属性

          Mol. FormulaC16H37NO
          Mol. Weight259.47
          Density0.995
          Refractive indexn20/D 1.405
          Flash Point11°C(lit.)
          TSCAYes
          Boiling Point>100
          Solubility溶于水。
          Stability对空气敏感，易吸潮
          Melting Point27-30 °C(lit.)
          Danger-Level甲类

          *以上化合物性质及应用等信息仅供参考