Acetyl chloride 乙酰氯

规格: 99%
CAS: 75-36-5
产品编号: H99956
MDL: MFCD00000719
品牌: INFI
Chemical NameAcetyl chloride
CAS Number75-36-5
PubChem Substance ID6367
EC Number200-865-6
Beilstein Registry Number605303
MDL NumberMFCD00000719
Synonym ACETYL CHLORIDE ACETYL CHLORIDE, REAGENTPLUS, >=99% ACETYL CHLORIDE, REAGENTPLUS, >=99% AKOS BBS-00003929 Acetic acid chloride; Acetic chloride Acetic acid monochloride Acetic chloride Acetyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN605303
Merck Number85
Chemical Name Translation乙酰氯
Wiswesser Line NotationGV1
LabNetwork Molecule IDLN00164431
InChIInChI=1S/C2H3ClO/c1-2(3)4/h1H3
Canonical SMILESCC(=O)Cl
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 910 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - spastic paralysis with or without sensory
   change
   Behavioral - excitement
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 32(3),48,1988

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 2 ppm/1M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   TGNCDL "Handbook of Organic Industrial Solvents," 2nd ed., Chicago, National
   Assoc. of Mutual Casualty Companies, 1961 Volume(issue)/page/year: 2,28,1961

WGK Germany1
Hazard Codes 3 F,C
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H351 Suspected of causing cancer 怀疑致癌
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
    RTECSAO6390000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P301+P330+P331+P310
    • P303+P361+P353
    • P305+P351+P338
    • P305+P351+P338+P310
    • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
    • P403+P233
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S1/2 None 上锁保管并避免儿童触及；
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R14 Reacts violently with water 遇水会猛烈反应
        • R22 Harmful if swallowed 吞咽有害
        • R34 Causes burns 会导致灼伤
        • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
        • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
          UN Number 1717
          Storage condition +4°C +4℃ 0-10 0-10°C 4 4℃ Moisture Sensitive Store at RT 充氩气保存;储存温度2-8°C 易挥发，对湿度敏感。
          Packing GroupII
          Hazard Class3/8
          Warnings 危化品目录(2015) 危险化学品
          Restrict -
        • 测定胆固醇及有机液体中的水分、测定羟基四乙基铅等，鉴定亚硝基。用作乙酰化试剂。用于制药的染料合成。
        • {ALD} Merck: 14,85
        • {uni_hambu
        • {ALD} Merck: 14,85
        • Beilstein:2(4)395
        • {uni_hamburg} Short: II/24B
          • 75-36-5 H99956 Acetyl chloride 乙酰氯

          化学属性

          Mol. FormulaCH3COCl
          Mol. Weight78.5
          Refractive indexn20/D 1.423
          Boiling Point52 °C(lit.)
          Density1.08
          Melting Point-115 - -109 °C
          Flash Point40 °F
          TSCAYes
          Autoignition Point1353 °F
          Vapor Density2.7 (vs air)
          Vapor Pressure11.69 psi ( 20 °C)
          SolubilityMiscible with benzene, chloroform, ether
          Stability对热敏感，湿度敏感
          Danger-Level-
          pH-:-
          Redox-

          *以上化合物性质及应用等信息仅供参考