三苯基锡化氢

规格:
CAS: 892-20-6
产品编号: HXYJ0000016186
MDL: MFCD00003004
品牌: Bellen
Chemical Name97% Triphenyltin hydride, 97%
Synonym TRIPHENYLSTANNANE 三苯基锡化氢 TRIPHENYLTIN HYDRIDE TRIPHENYLTIN 三苯基氢化锡 triphenyl-stannan Triphenylzinnhydrid Triphenylhydridetin(IV) Triphenyltin Triphenylstannane Triphenylstannyl hydride triphenyl stannane Triphenyl-stannane Triphenyltin hydride Stannane, triphenyl- triphenylstannylhydride
MDL NumberMFCD00003004
CAS Number892-20-6
PubChem Substance ID24854702
EC Number212-967-8
Beilstein Registry Number3544353
Chemical Name Translation三苯基氢化锡,
LabNetwork Molecule IDLN02145090
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 81 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7900 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 491 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8500 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

WGK Germany3
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311+H331
    Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
    Precautionary statements
    • P273 Avoid release to the environment. 避免释放到环境中。
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P301+P310
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
    • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
    • P301+P310+P330
    • P304+P340+P312
    • P302+P352+P312
      Signal word Danger
      RTECSWH8882000
      Packing GroupIII
      UN Number UN 3077 9/PG 3 UN3146
      Risk Statements
      • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
      • R50/53
        Safety Statements
        • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
        • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
        • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
        • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
        • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
        • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
        • S27/28
          Storage condition Air & Moisture Sensitive 0-6°C
          Hazard Codes T,N
          Hazard Class6.1
        • {ALF} For general reactions of organotin hydrides, see Tri-n-butyl­tin hydride, A13298.
        • {ALF}
        • {ALF} 2-(Bromomethyl)penicillin V methyl ester undergoes ring-expansion via the methylene radical, to give the corresponding cepham: Tetrahedron, 44, 5953 (1988):
        • {uni_hamburg} Short: III/35C4
        • {ALF} Hydrostannylation of terminal alkynes is conveniently carried out in the presence of triethylboron. Reaction is faster than with tributyl tin hydride and gives higher yields. Stereoselectivity varies from 69-100% (E): Tetrahedron, 45, 923 (1989):
        • {uni_hamburg} Short: EINECS
        • {ALF} Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the corresponding methylenedioxy compounds: J. Org. Chem., 62, 1690 (1997).
        • {ALF} Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the correspond
          • 892-20-6 HXYJ0000016186 三苯基锡化氢

          化学属性

          Mol. Formula(C6H5)3SnH
          Mol. Weight351.03
          Refractive indexn20/D 1.632(lit.)
          Boiling Point163-165 °C/0.3 mmHg(lit.)
          Density1.374 g/mL at 25 °C(lit.)
          Melting Point28 °C(lit.)
          Flash Point>110°(230°F)
          TSCANo