研峰科技 Infinity Scientific

三苯基锡化氢

规格:

CAS: 892-20-6

产品编号: HXYJ0000016186

MDL: MFCD00003004

品牌: Bellen

Chemical Name	Triphenyltin Hydride
Synonym	Triphenyltin hydride {LY} Triphenyltin hydride {} {LY} Triphenyltin hydride {} {} {LY} Triphenyltin hydride {} {} {} {LY} Triphenyltin hydride {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Triphenyltin hydride {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00003004
CAS Number	892-20-6
PubChem Substance ID	24854702
EC Number	212-967-8
Beilstein Registry Number	3544353
Chemical Name Translation	三苯基氢化锡
LabNetwork Molecule ID	LN02145090
Canonical SMILES	C1([SnH](C2=CC=CC=C2)C3=CC=CC=C3)=CC=CC=C1

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 81 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7900 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 491 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8500 ug/kg
TOXIC EFFECTS :
   Behavioral - muscle weakness
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,591,1969

WGK Germany	3
Hazard statements
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。 H331 Toxic if inhaled 吸入中毒 H311 Toxic in contact with skin 皮肤接触中毒 H301 Toxic if swallowed 吞食有毒 H301+H311+H331
Personal Protective Equipment	dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Precautionary statements
P273 Avoid release to the environment. 避免释放到环境中。 P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P301+P310 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P501 Dispose of contents/container to..… 处理内容物/容器..... P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。 P301+P310+P330 P304+P340+P312 P302+P352+P312
Signal word	Danger
RTECS	WH8882000
Packing Group	III
UN Number	UN 3077 9/PG 3 UN3146
Risk Statements
R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒 R50/53
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗； S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置； S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书； S27/28
Storage condition	2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air & Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes	T,N
Hazard Class	6.1

{ALF} For general reactions of organotin hydrides, see Tri-n-butyltin hydride, A13298.

{ALF}

{ALF} 2-(Bromomethyl)penicillin V methyl ester undergoes ring-expansion via the methylene radical, to give the corresponding cepham: Tetrahedron, 44, 5953 (1988):

{uni_hamburg} Short: III/35C4

{ALF} Hydrostannylation of terminal alkynes is conveniently carried out in the presence of triethylboron. Reaction is faster than with tributyl tin hydride and gives higher yields. Stereoselectivity varies from 69-100% (E): Tetrahedron, 45, 923 (1989):

{uni_hamburg} Short: EINECS

{ALF} Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the corresponding methylenedioxy compounds: J. Org. Chem., 62, 1690 (1997).

{ALF} Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the correspond

化学属性

Mol. Formula	C18H16Sn
Mol. Weight	351.03
Refractive index	n20/D 1.632(lit.)
Boiling Point	163-165 °C at 0.3 mmHg
Density	1.374
Melting Point	28 °C
Flash Point	>110°(230°F)
TSCA	No

*以上化合物性质及应用等信息仅供参考