三氟甲烷磺酸锌 三氟甲烷磺酸锌

规格:
CAS: 54010-75-2
产品编号: HXYJ0000017500
MDL: MFCD00013229
品牌: Bellen
Chemical NameZinc Trifluoromethanesulfonate
Synonym Bis(trifluoromethanesulfonato)zinc Bis(trifluoromethanesulfonato)zinc Zinc trifluoromethylsulfonate Zn(OTf)2 Zn(OTf)2 三氟甲基磺酸 锌盐 三氟甲磺酸锌 Zinc triflate Zinc trifluoromethylsulfonate 三氟甲基磺酸 锌盐 三氟甲基磺酸 锌盐;三氟甲磺酸锌;三氟甲磺酸锌(II);三氟甲烷磺酸锌(II) 三氟甲烷磺酸锌
EC Number258-922-6
Beilstein Registry Number4028195
PubChem Substance ID87577065
Reaxys-RN4028195
Chemical Name Translation三氟甲烷磺酸锌
LabNetwork Molecule IDLN00222982
InChIKeyCITILBVTAYEWKR-UHFFFAOYSA-L
MDL NumberMFCD00013229
CAS Number54010-75-2
GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
    Packing GroupIII
    UN Number 3261
    Risk Statements
    • R34 Causes burns 会导致灼伤
      Storage condition Hygroscopic
      WGK Germany3
      Precautionary statements
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
      • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
      • P301+P330+P331
      • P303+P361+P353+P310+P363
      • P304+P340
      • P304+P340+P310
      • P305+P351+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
      • P405 Store locked up. 上锁保管。
      • P501 Dispose of contents/container to..… 处理内容物/容器.....
        Hazard statements
        • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
          Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
          Signal word Danger
          Hazard Codes 8 C
          Hazard Class8
        • 糖苷化方法中的常用试剂； 合成二硫代缩酮（dithioketals）的催化剂
        • {ALF} In combination with N-methylephedrine, catalyzes enantioselective addition of terminal alkynes to aldehydes to give propargylic alcohols in high yield and ee: J. Am. Chem. Soc., 122, 1806 (2000).
        • {ALF} Mild Lewis acid catalyst which promotes thioketalization, particularly of acid-sensitive substrates, with ethanedithiol: Tetrahedron Lett., 24, 169 (1983); J. Am. Chem. Soc., 105, 1662 (1983).
        • {ALF} Useful, alone or in combination with TMS chloride, for glycosidation reactions: Chem. Pharm. Bull., 40, 2909 (1992); 41, 201 (1993); 42, 1808 (1994).
        • {ALF} Promotes the aldol reaction of silyl enol ethers with aldehydes: Gazz. Chim. Ital., 123, 673 (1993).
          • 54010-75-2 HXYJ0000017500 三氟甲烷磺酸锌 三氟甲烷磺酸锌

          化学属性

          Melting Point>=300 °C(lit.)
          TSCAYes
          Density4.43
          SolubilitySoluble in water.
          Mol. Formula2
          Mol. Weight364
          Appearance white pwdr.
          Stabilityhygroscopic

          *以上化合物性质及应用等信息仅供参考