(2S,3S)-(+)-1,4-Bis(diphenylphosphino)-2,3-O-isopropylidene-2,3-butanediol (+)-异丙烯-2,3-二羟-1,4-双二丙基膦丁烷

规格: 98%
CAS: 37002-48-5
产品编号: H33388
MDL: MFCD00009760
品牌: INFI
Chemical Name(+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane
Synonym (+)-2,3-O-Isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)butane (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (+)-1,4-双(二苯基膦)-1,4-二脱氧-2,3-O-异亚丙基-D-苏糖醇 (+)-DIOP (4S,5S)-4,5-双(二苯基膦甲基)-2,2-二甲基-1,3-二氧戊环 (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (S,S)-DIOP (+)-2,3-O-异丙烯基-2,3-二羟基-1,4-双(二苯基膦)丁烷 (+)-DIOP (+)-1,4-双(二苯基膦)-1,4-二脱氧-2,3-O-异亚丙基-D-苏糖醇 (4S,5S)-4,5-双(二苯基膦甲基)-2,2-二甲基-1,3-二氧戊环 (4S-反式)-[(2,2-二甲基-1,3-二氧戊环-4,5-二基)双(亚甲基)]双(二苯基膦) (S,S)-DIOP
MDL NumberMFCD00009760
PubChem Substance ID87564055
Beilstein Registry Number1630280
CAS Number37002-48-5
EC Number253-307-9
Reaxys-RN5148912
Chemical Name Translation异丙烯-2,3-二羟-1,4-双二丙基膦丁烷
GHS Symbol
WGK Germany3
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P305+P351+P338
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Hazard Codes Xi
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Signal word
      Safety Statements
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Air Sensitive
        • {SA}
        • Morimoto, T. et al. Tetrahedron Asymmetry 6 , 23, (1995)
        • {SA}
        • Morimoto, T. at al. Tetrahedron Asymmetry 6 , 75, (1995)
        • {SA}
        • Matsumoto, Y. et al. Tetrahedron 50 , 335, (1994)
        • {SA}
        • Sato, Y. et al. Tetrahedron 50 , 371, (1994)
        • {SA}
        • Gladiali, S. Pinna, L. Tetrahedron Asymmetry 1 , 693, (1990)
        • {SA}
        • Fieser 4 ,273 / Fieser 5 ,360 / Fieser 6 ,309 / Fieser 9 ,259 / Fieser 11 ,277 / Fieser 13 ,153
        • {SA}
        • Aldrich MSDS 1 , 1121:B / Corp MSDS 1 (1), 2037:A / FT-IR 2 (2), 3322:C / FT-IR 1 (2), 542:A / FT-NMR 1 (2), 1662:B / NMR-Reference 2 (2), 879:D / RegBook 1 (2), 2267:J / Sigma FT-IR 1 (2), 671:B / Structure Index 1 , 355:E:3
        • {ALFA} Ligand for the in situ preparation of chiral hydrogenation catalysts: J. Am. Chem. Soc., 94, 6429 (1972); Helv. Chim. Acta, 57, 2487 (1974); J. Org. Chem., 44, 3741 (1979).
        • {ALF} Ligand for the in situ preparation of chiral hydrogenation catalysts: J. Am. Chem. Soc., 94, 6429 (1972); Helv. Chim. Acta, 57, 2487 (1974); J. Org. Chem., 44, 3741 (1979).
          • 37002-48-5

          化学属性

          Mol. FormulaC31H32O2P2
          Mol. Weight498.55
          Melting Point87-91°C
          TSCANo
          Appearance white pwdr.
          Stabilityair sensitive
          Density1.0

          *以上化合物性质及应用等信息仅供参考