(S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂

规格: 99%
CAS: 210169-54-3
产品编号: H76058
MDL: MFCD09753005
品牌: INFI
Chemical Name(S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole
Synonym (R)-(+)-5,5′-双(二苯基膦)-4,4′-二-1,3-苯并二噁茂 [4(R)-(4,4′-二-1,3-苯并二噁茂)-5,5′-二基]双[二苯基膦] (S)-(-)-5,5′-双(二苯基膦)-4,4′-二-1,3-苯并二噁茂 (S)-SEGPHOS®
MDL NumberMFCD09753005
CAS Number210169-54-3
Chemical Name Translation(S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂
Reaxys-RN11841467
PubChem Substance ID329761551
WGK Germany3
  • {SA} Gao, X.; et al., Enhanced anti-Diastereo- and Enantioselectivity in Alcohol-Mediated Carbonyl Crotylation Using an Isolable Single Component Iridium Catalyst J. Org. Chem. 76 , 2350-2354, (2011)
  • {SA} Guo, X.-X.; et al., Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes Tetrahedron Asymmetry 21 , 1730-1736, (2010)
  • {SA} Maeda, T.; et al., Diastereo- and Enantioselective Hydrogenation of α-Amino-β-Keto Ester Hydrochlorides Catalyzed by an Iridium Complex with MeO-BIPHEP and NaBArF: catalytic Cycle and Five-Membered Chelation Mechanism of Asymmetric Hydrogenation Chem. Eur. J. 16 , 11954-11962, (2010)
  • {SA} Miura, T.; et al., Nickel-Catalyzed Denitrogenative Annulation Reactions of 1,2,3-Benzotriazin-4(3H)-ones with 1,3-Dienes and Alkenes J. Org. Chem. 75 , 5359-5362, (2010)
  • {SA} Ogaki, S.; et al., Enantioselective Synthesis of Axially Chiral Hydroxy Carboxylic Acid Derivatives by Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition J. Org. Chem. 76 , 1926-1929, (2011)
  • {SA} Suda, T.; et al., Rhodium-Catalyzed Asymmetric Formal Olefination or Cycloaddition: 1,3-Dicarbonyl Compounds Reacting with 1,6-Diynes or 1,6-Enynes Angew. Chem. Int. Ed. Engl. 50 , 4475-4479, (2011)
    • 210169-54-3

    化学属性

    Mol. FormulaC38H28O4P2
    Mol. Weight611
    Melting Point168-172°C
    Appearance off-white pwdr.
    Density1.0

    *以上化合物性质及应用等信息仅供参考