Triruthenium dodecacarbonyl 十二羰基三钌

规格: 99%
CAS: 15243-33-1
产品编号: H84731
MDL: MFCD00011209
品牌: INFI
Chemical NameRuthenium Carbonyl
Synonym Triruthenium Dodecacarbonyl
MDL NumberMFCD00011209
PubChem Substance ID87558750
CAS Number15243-33-1
EC Number239-287-4
Reaxys-RN14281346
Chemical Name Translation十二羰基三钌
InChIKeyNQZFAUXPNWSLBI-UHFFFAOYSA-N
LabNetwork Molecule IDLN00239128
Canonical SMILES[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1
  • 羰基团的前提和H-转移催化剂。用于芳香族硝基复合物至氨基甲酸盐的还原性羰基化。
  • {uni_hamburg} Short: III/35D5
  • {ALF} On heating under pressure with norbornene and CO, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998). For reaction scheme, see 2-Hexyne, B22405.
  • {ALF}
  • {ALF} 1,6-Enynes undergo cyclocondensation with CO under pressure, to give bicyclo[3.3.0]octenones: J. Org. Chem., 62, 3762 (1997):
  • {SA} FT-IR 2 (3), 4592:B / FT-IR 1 (2), 1299:D / RegBook 1 (2), 3143:B
    • 15243-33-1 H84731 Triruthenium dodecacarbonyl 十二羰基三钌

    化学属性

    Mol. FormulaC12O12Ru3
    Mol. Weight639.33
    Melting Point147 - 153 °C
    SolubilitySparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. Solutions undergo some decomposition on strong heating
    TSCAYes
    Appearance orange xtl.
    Density1.0

    *以上化合物性质及应用等信息仅供参考